Lecture Summary


Week 1- week 5

(Gums and stabilizers)

FOOD HYDROCOLLOIDS= A RANGE OF POLYSACCHARIDES AND PROTEINS
-GUMS', 'STABILIZERS'
Functions:
primary:
  • Thickening agent
  • Gelling or texturizing agents
Secondary:
  • Stabilisation of emulsion
  • Suspension of particulates
  • Control of cystallisation
  • Encapsulation
  • Formation of film

use<2%, if> 2%=very viscous

hydrocolloid.jpg
structure of hydrocolloid polymer


Factors affect gum properties

  • molecular weight
  • monosaccharide composition
  • type of chains
  • number of side chains
  • distribution of side chains


Main classes of Hydrocolloids
  • derivatives from exudation or sap of tree
  • extract from seed (Locust bean gum)
  • extract from seaweeds (carrageenan)
  • microbial gum (xanthan gum)
  • extract from tubers (konjac)
  • extract from plant parts (pectin)


Thermoreversible gelling agents
*Gel formed on heating or cooling and the process is reversible
eg: gelatin, agar, kappa-carrageenan, Iota-carrageenan, LM pectin, HPMC.


Thermally irreversible gelling agents

*heating will not form solution
eg: alginate, starch, konjac, HM pectin.

Pectin

  • derived from peel of citrus fruits, apple pomace, sugar beet, sunflower heads.
  • types of pectin---High methoxyl pectin (HMP), DE> 50%


pectin.jpg

High methoxyl pectin (HMP)

  • DE---58% to 75%
  • to form gel, soluble solid content 55-85%, pH 2.8-3.8. (e.g. jam and jellies)
  • ultrarapid/rapid set (DE as high as 77)---used in jam with whole fruits, to ensure uniform distribution of fruits particles.
  • slow set (DE~58) ---used in very acid fruits such as blackcurrant to avoid premature gelation.

jam_pectin.jpg


Low methoxyl pectin (LMP)
- DE < 50% — two sub-groups: Conventional low methoxyl pectin (LMP) and Amidated low methoxyl pectin (ALMP)
- Form gels in the presence of Ca2+, with a low solids content & wide pH range (1-7) [but soluble solids can be up to 85%]
- LMP – less Ca2+ reactive than ALMP ⇒ used as a thickening agent in yoghurt fruit
- ALMP – very Ca2+ reactive ⇒ assist gelation in low sugar fruit preparations, e.g. low-sugar jams & jellies



jelly.jpg
Guar Gum
  • a linear chain of mannose with single galactose units atteched as side chains
  • more highly substituted than LBG
  • more soluble and hydrate fully in cold water giving high viscosity
  • non gelling- for stabilizer and water binding

guar_gum.jpg
chemical structure of guar gum

Carrageenan
  • kappa-Carrageenan
  • Lambda-Carrageenan (cannot form gel)
  • Iota-Carrageenan


meat.jpgice_cream2.jpg


chocolate_milk